Kinetics of Electron Transfer Reaction Between Co(II) and Chlorate Ions: Isothermal Reactor Design and Experimental Validation

The Batch Stirred Tank Reactor (BSTR) has been commonly used for decades in the chemical process industries and even on a pilot plant or laboratory scale whenever expensive and delicate raw materials and products such as pharmaceuticals or fragile transition metal complexes are involved. This research article describes the details of isothermal BSTR and subsequent experimental validation of the rate law discovered in the previous paper of this series on the electron transfer reaction between Co(II) and chlorate ions in acetic acid solution. A Series of tests were performed to evaluate the efficiency of the BSTR at multiple temperatures and illustrate the differences between the theoretical and experimental conversion of potassium chlorate through relative error. The experimental conversions are calculated with the design equation. Theoretical and experimental conversions are correlated and proportional to the initial concentrations of the reactant and electron transfer reaction among the reactants. Based on the parameters of the design equation, a set with average parameters was chosen and tested over BSTR. The model was then validated for different temperatures and conversions. A design equation for the BSTR has been written and applied for the conversions of 25%, 50%, 75%, and 95%. The time interval is going to be predicted by the model to achieve the desired conversions. The percent relative error between predicted and experimental conversions clearly shows the model's predictability, power, and reliability. The precision of the observed rate constant for the electron transfer reaction is found to be 2.2023×〖10〗^(-2 )%

Mahwish M. Khan