Composites from polyimide and epoxy-amine were prepared aiming for enhancing its thermal and mechanical properties. Polyimide-epoxy-amine hybrid films were prepared by blending of polyimide and epoxy-amine in different ratios whereas, polyimide was prepared by reacting 1,2-di(p-aminophenyloxy)ethylene with 3,3¢4,4¢-benzophenone tetracrboxylic acid dianhydride. The blend systems with Araldite LY564 (1,4-butanediolediglycidyl ether) (BDDE) and Hardener HY2954 (3,3¢-dimethyl-4,4¢-diaminodicyclohexyl)methane (MACM) were investigated in term of thermal, mechanical and viscoelastic measurements. Thermal stability was determined using thermogravimetric analysis. The effect of the polyimide content on the glass transition temperature (Tg) and thermal stability was observed. Viscoelastic measurements showed that the glass transition temperature shifted with the increase of polyimide content. The composites showed higher thermal stability in comparison with neat epoxy-amine matrix for higher polyimide concentration. The effect of polyimide content on the mechanical properties was also investigated. The tensile measurements of the films showed that with the increase of polyimide content the tensile modulus of the films was increased.


MUHAMMAD ZAFAR-UZ ZAMAN ,ZAREEN AKHTER ,MUHAMMAD SAEED BUTT ,MUHAMMAD SHOAIB ,HUMAIRA MASOOD SIDDIQI ,