Ylide CpPMePh2 was synthesized by the deprotonation of Ylide salt of iodide by using different deprotonating agent like n butyl Li, NaH, (CH3)2N Li, isopropyl Li and ((CH3)3Si)2N.Li. Out of all these deprotonating agents only ((CH3)3Si)2N.Li gave pure and better yield. Its complex of Ru was synthesized. A RuCl2(PPh3)3 complex reacted with the freshly synthesized Ylide gave successful required ruthenium complex. The synthesized [Ru(PPh3)3(CpPMePh2)2]Cl2 complex was analyzed and verified by 1H and 31P NMR.
Syeda Robina Gilani ,
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