The stoichiometry between permanganate and cyanide ions in aqueous solution has been investigated. The reaction leading to the formation of a dark brown precipitate is represented by the equation   2MnO4-  + 3CN-  +  H2O  =  2MnO2  +  3OCN-  +  2OH-   Interaction of excess of ice-cooled 3M aqueous potassium cyanide and 0.1M aqueous potassium permanganate, initially produces and unstable manganese (IV) cyano species wich is finally reduced to manganese (III) giving heptapotassium- u-Oxo-bis [pentacyanomanganate(III)] cyanide. The oxo bridged [Mn2O(CN)10]6- ion appears to exist in solution.


A M QURESHI ,S A SUBAIRI ,